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Palladium-catalyzed thio- and selenocarbonylation of 2-iodoglycals

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dc.contributorLab. Bioquímicapt_BR
dc.contributor.authorDarbem, Mariana P.pt_BR
dc.contributor.authorEsteves, Henrique A.pt_BR
dc.contributor.authorOliveira, Isadora M. dept_BR
dc.contributor.authorPimenta, Daniel Carvalhopt_BR
dc.contributor.authorStefani, Hélio A.pt_BR
dc.date.accessioned2020-07-09T21:27:45Z-
dc.date.available2020-07-09T21:27:45Z-
dc.date.issued2020pt_BR
dc.identifier.citationDarbem MP., Esteves HA., Oliveira IM., Pimenta DC, Stefani HA.. Palladium-catalyzed thio- and selenocarbonylation of 2-iodoglycals. ChemCatChem. 2020 Jan;12:576-583. doi:10.1002/cctc.201901403.pt_BR
dc.identifier.urihttps://repositorio.butantan.gov.br/handle/butantan/3036-
dc.description.abstractThe carbonylative cross-coupling reactions of 2-iodoglycals with thiols and selenols in the presence of molybdenum hexacarbonyl as a solid source of carbon monoxide is described. This methodology permitted the synthesis of 29 C2-glycosides bearing thioester and selenoester functionalities in moderate to excellent yields and high functional group tolerance. Moreover, this communication describes the first catalytic carbonylative coupling reaction of selenols with a carbon electrophile.pt_BR
dc.description.sponsorship(FAPESP) Fundação de Amparo à Pesquisa do Estado de São Paulopt_BR
dc.description.sponsorship(CNPq) Conselho Nacional de Desenvolvimento Científico e Tecnológicopt_BR
dc.format.extent576-583pt_BR
dc.language.isoEnglishpt_BR
dc.relation.ispartofChemcatchempt_BR
dc.rightsRestricted accesspt_BR
dc.titlePalladium-catalyzed thio- and selenocarbonylation of 2-iodoglycalspt_BR
dc.typeArticlept_BR
dc.identifier.doi10.1002/cctc.201901403pt_BR
dc.identifier.urlhttps://doi.org/10.1002/cctc.201901403pt_BR
dc.contributor.external(USP) Universidade de São Paulopt_BR
dc.identifier.citationvolume12pt_BR
dc.subject.keywordthiocarbonylationpt_BR
dc.subject.keywordselenocarbonylationpt_BR
dc.subject.keywordC2-branched sugarspt_BR
dc.subject.keywordglycalspt_BR
dc.subject.keywordmolybdenum hexacarbonylpt_BR
dc.relation.ispartofabbreviatedChemCatChempt_BR
dc.identifier.citationabntv. 12, p. 576-583, jan. 2020pt_BR
dc.identifier.citationvancouver2020 Jan;12:576-583pt_BR
dc.contributor.butantanPimenta, Daniel Carvalho|:Pesquisador:Docente Permanente PPGTOX|:Lab. Bioquímica|:pt_BR
dc.sponsorship.butantan(CNPq) Conselho Nacional de Desenvolvimento Científico e Tecnológico¦¦302418/2018-0pt_BR
dc.sponsorship.butantan(FAPESP) Fundação de Amparo à Pesquisa do Estado de São Paulo¦¦2017/24821-4pt_BR
dc.sponsorship.butantan(FAPESP) Fundação de Amparo à Pesquisa do Estado de São Paulo¦¦2016/24396-9pt_BR
dc.sponsorship.butantan(FAPESP) Fundação de Amparo à Pesquisa do Estado de São Paulo¦¦2017/26673-2pt_BR
dc.sponsorship.butantan(FAPESP) Fundação de Amparo à Pesquisa do Estado de São Paulo¦¦2016/04289-3pt_BR
dc.identifier.bvsccBR78.1pt_BR
dc.identifier.bvsdbIBProdpt_BR
dc.description.dbindexedYespt_BR
item.fulltextSem Texto completo-
item.languageiso639-1English-
item.openairetypeArticle-
item.grantfulltextnone-
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