Palladium-catalyzed thio- and selenocarbonylation of 2-iodoglycals


Publication type
Article
Appears in Collections:
Metrics
Abstract
The carbonylative cross-coupling reactions of 2-iodoglycals with thiols and selenols in the presence of molybdenum hexacarbonyl as a solid source of carbon monoxide is described. This methodology permitted the synthesis of 29 C2-glycosides bearing thioester and selenoester functionalities in moderate to excellent yields and high functional group tolerance. Moreover, this communication describes the first catalytic carbonylative coupling reaction of selenols with a carbon electrophile.
Reference
Darbem MP., Esteves HA., Oliveira IM., Pimenta DC, Stefani HA.. Palladium-catalyzed thio- and selenocarbonylation of 2-iodoglycals. ChemCatChem. 2020 Jan;12:576-583. doi:10.1002/cctc.201901403.
Link to cite this reference
https://repositorio.butantan.gov.br/handle/butantan/3036
Journal title
Issue Date
2020


Files in This Item:

Existing users please Login
10.1002cctc.201901403.pdf
Size: 1.39 MB
Format: Adobe PDF
Embargoed until January 1, 2999    Request a copy
Show full item record

The access to the publications deposited in this repository respects the licenses from journals and publishers.